Single-tone mid-infrared frequency modulation spectroscopy for sensitive detection of transient species

Supporting Information for Mid-Infrared Time-Resolved Frequency Comb Spectroscopy of Transient Free Radicals

Mid-Infrared Time-Resolved Frequency Comb Spectroscopy of Transient Free Radicals.

We demonstrate time-resolved frequency comb spectroscopy (TRFCS), a new broadband absorption spectroscopy technique for the study of trace free radicals on the microsecond timescale. We apply TRFCS to study the time-resolved, mid-infrared absorption of the deuterated hydroxyformyl radical trans-DOCO, an important short-lived intermediate along the OD + CO reaction path. Directly after photolysi...

Frequency-comb-referenced mid-infrared source for high-precision spectroscopy.

We report on a tunable continuous-wave mid-infrared optical parametric oscillator (OPO), which is locked to a fully stabilized near-infrared optical frequency comb using a frequency doubling scheme. The OPO is used for 40 GHz mode-hop-free, frequency-comb-locked scans in the wavelength region between 2.7 and 3.4 μm. We demonstrate the applicability of the method to high-precision cavity-ring-do...

Mid-infrared wavelength- and frequency-modulation spectroscopy with a pump-modulated singly-resonant optical parametric oscillator.

We describe the implementation of the wavelength- and frequency-modulation spectroscopy techniques using a singly-resonant optical parametric oscillator (OPO) pumped by a fiber-amplified diode laser. Frequency modulation of the diode laser was transferred to the OPO's mid-infrared idler output, avoiding the need for external modulation devices. This approach thus provides a means of implementin...

Frequency comb assisted mid-infrared spectroscopy of cold molecular ions.

A mid-infrared spectrometer consisting of a high power optical parametric oscillator, a frequency comb, and a cold ion trap is described and characterized. The idler frequency at 3 μm is measured accurately by analyzing the pump and signal beat frequencies with the comb. This is done via two spectrum analyzers, allowing for a wide and continuous scanning ideal for spectroscopy of cold molecules...